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البحوث العلمية

2024

Green polymer electrolyte and activated charcoal-based supercapacitor for energy harvesting application: Electrochemical characteristics

2024-01
Green Processing and Synthesis (القضية : 1) (الحجم : 13)
The aim of this study is to address the growing concern about microplastics in the ocean and their potential harm to human health through ingestion. The MPs issue is largely a result of the increasing demand for electronic devices and their components. To tackle this challenge, the research aimed to develop a green polymer electrolyte that used glycerol as a plasticizing agent to improve ionic conductivity. The polymer host included chitosan and polyvinyl alcohol and was composed of sodium acetate. To evaluate the performance of the polymer electrolyte, various analytical techniques were used, including impedance and electrochemical studies. The ionic conductivity of 7.56 × 10−5 S·cm−1 was recorded. The dielectric property study confirmed the ionic conduction process in the system and revealed the existence of non-Debye type relaxation, as indicated by asymmetric peaks of tanδ spectra. The alternating conductivity exhibits three distinguished regions. The polymer electrolyte was discovered to be electrochemically stable up to 2.33 V and capable of storing energy as a non-Faradaic electrochemical double-layer capacitor (EDLC). The cyclic voltammetry pattern is a leaf like shape. The EDLC was able to be charged and discharged up to 1 V, and it showed cyclability and could be used in low-voltage applications.
2023

The study of ion transport parameters connected with Na+ ion dynamics in biopolymer electrolytes through electrical equivalent circuits: Dielectric and electrochemical properties

2023-10
Results in Physics (الحجم : 54)
Non-toxic materials including polymers and salts meet global demand for renewable energy and they are crucial to be considered in the energy storage application. In this study, the appropriateness of solid biopolymer electrolytes for energy storage applications is examined, as these materials have the potential to overcome the limitations of conventional liquid electrolytes. The solution casting method to generate membranes of ion-conducting polymer blend-based electrolytes from a methylcellulose-dextran (MC:DEX) blend mixed with sodium acetate (NaCH3COO) to act as an Na+ supply, and glycerol to serve as a plasticizer. The electrochemical impedance measurement is performed to determine several transport parameters, including density number (n), mobility (µ), and diffusion coefficient (D). The highest glycerol content resulted in an ionic conductivity of 8.87×10−5 S cm−1. Furthermore, the electrical properties of the electrolytes are investigated, including dielectric, AC conductivity and electric modulus parameters. The maximum plasticized system was found to have an ion transference number of 0.98, indicating that ions played a critical role in the charge transfer mechanisms. Linear sweep voltammetry analysis demonstrated the stability of the maximum conductive sample up to 2.3 V.

A comprehensive comparative study of some corrosion inhibitors using different techniques

2023-10
Hybrid Advances (الحجم : 4)
Corrosion is a serious problem in industry of metals particularly in the areas which possess high amount of moisture. Due to this reason scientists and researchers have been investigated several methods to overcome this issue. They have discovered many inhibitors to reduce the hazards of corrosion to metals. Throughout history many changes and developments have been done to increase the quality of these corrosion inhibitors. In this study some corrosion inhibitors from different works and researches have been analyzed through the comparisons of the practical data obtained from the techniques such as TEM, XPS and Langmuir adsorption isotherm. The inhibitors involved: Novel nitrogen doped carbon dots (NCDs), imidazole-citric acid-based carbon dots and Novel N-doped carbon dots (CDs) were synthesized via pyrolysis of ammonium citrate. The inhibitors, with various ratios, were applied to the surface of Q235 carbon steel in various intervals of times in the presence absence of hydrochloric acid solution. All of results reveal to improvement and reducing the corrosion on metals. The inhibitors have shown physical and chemical adsorption based on the Langmuir adsorption model. The reason behind selecting specific researches in this work was to analyze the progress of the carbon dot-based corrosion inhibitors and assisting researchers and industries to choose the most effective scientific approach.

Biosynthesis of Al-doped ZnO nanoparticles with different Al doping ratio for methylene orange dye degradation activity

2023-08
Ceramic International
Al-doped ZnO nanoparticles were synthesized using the green method for dye degradation activity for the first time. The Allium Calocephalum Wendelbow (ACW) plant leaf extract has been employed in the biosynthesis of the aluminum (Al) doped and undoped (pure) zinc oxide (ZnO) nanoparticles (NPs) for the applicability of dye degradation capability. In order to investigate the dye degradation behavior process, methylene orange (MO) is being used. For produced Al-doped and undoped ZnO NPs, the efficiency and sustainability of the (ACW) leaf plant for the dye decomposition process has been examined. The produced Al-doped and pure ZnO NPs have been studied for their quality and structure using a variety of characterization technique. For the first time, the green synthesis process was applied in order to thoroughly examine the impact of the various Al-doped green ZnO nanoparticle ratios on the average size, shape, distribution, crystal structure, functional group, optical capabilities, chemical compositions, and energy band-gap. The ratio of Al-doped ZnO NPs consisted of 0% (pure), 0.025%, 0.050%, 0.075%, 0.10%, and 0.20%. The results demonstrate that the characteristics of the doped and pure green ZnO NPs are significantly affected by the varied Al-doped ZnO ratio. ACW plant leaf extract was examined using FTIR and UV–Visible spectroscopy, and the results suggested that this extract might be a promising alternative for the environmentally friendly synthesizing of both doped and undoped ZnO NPs. At ambient temperature, the UV–Visible spectra of leaf extract displayed two separate absorption peaks roughly at 262 nm and 350 nm. As additional proof of the ACW plant's use of the green method in this research, the examination of the MO dye degrading activity by Al-doped and pure ZnO NPs was conducted utilizing the newly produced Al-doped and pure ZnO NPs made to utilize the green technology. The Al-doped ZnO NPs produced at a ratio of 0.075% displayed a significant degradation rate percentage when dye degradation ability was measured with UV light. Also, the average dye degradation percentage of 90.5% for 80 min of the fabricated Al-doped green ZnO NPs displayed a quicker than average dye degradation percentage of 74% for 140 min of the fabricated pure green ZnO NPs.

A high responsivity, fast response time of ZnO nanorods UV photodetector with annealing time process

2023-07
Optical Materials (الحجم : 141)
We reveal the development of ZnO nanorods (NRs) onto seedling layers via utilizing chemical bath deposition (CBD) technique. In this paper, the influences of six various annealing times on characteristics of the ZnO NRs were explored and reported. The sample's nano-morphological, structural as well as optical characteristics were investigated via utilizing field emission scanning electron microscopy, XRD diffraction system, photoluminescence (PL), as well as a UV–Vis spectrophotometer. The best sample of ZnO NRs positioning and connecting metal semiconductor metal photodetector was created. The UV-device had a sensitivity of 334% with a low dark current after exposed to wavelength of 390 nm UV-light (0.57 mW/cm2) under −5 V applied voltage. Furthermore, photo-response peak was 2.19 A/W and the response times as well as recovery time were 0.49, 1.14 s, respectively. This novel technique offers an inexpensive substrate and simple process for controlling the synthesis of the nanorods, as well as demonstrating the feasibility of building nano-scale UV detectors for nano-optics application fields.

Impact of Growth Temperature of Lead-Oxide Nanostructures on the Attenuation of Gamma Radiation

2023-06
ACS Omega (القضية : 8) (الحجم : 24)
Chemical bath deposition (CBD) technique is utilized to grow lead-oxide (PbO) nanostructures (NSs) over PbO seed fabricated by physical vapor deposition (PVD) method on glass substrates. The effect of growth temperatures 50 and 70 °C on the surface topography, optical properties, and crystal structure of lead-oxide NSs has been studied. The investigated results suggested that the growth temperature has a huge and very considerable influence on the PbO NS, and the fabricated PbO NS has been indexed as the Pb3O4 polycrystalline tetragonal phase. The crystal size for PbO thin films grown at 50 °C was 85.688 nm and increased to 96.61 nm once the growth temperature reached 70 °C. The fabricated PbO nanofilms show a high rate of transmittance, which are ∼70 and 75% in the visible spectrum for the films deposited at 50 and 70 °C, respectively. The obtained Eg was in the range of 2.099–2.288 eV. Also, the linear attenuation coefficient values of gamma-rays for shielding the Cs-137 radioactive source increased at 50 °C. The transmission factor, mean free path, and half-value layer are reduced at a higher attenuation coefficient of PbO grown at 50 °C. This study evaluates the relationship between synthesized lead-oxide NSs and the radiation energy attenuation of gamma-rays. This study provided a suitable, novel, and flexible protective shield of clothes or an apron made of lead or lead oxide to protect against ionizing radiation that meets safety rules and protects medical workers from ionizing radiation.

Sunlight harvesting for heat generation inside water using biosynthesized magnetite nanoparticles

2023-04
Biomaterials Science (القضية : 2)
A low-cost, simple, inexpensive, and environmentally friendly method has been employed for synthesizing magnetite nanoparticles (Fe3O4 NPs). In this study, weeping willow (Salix babylonica L.) aqueous leaf extract has been utilized as a reducing, capping, and stabilizing agent. The synthesized Fe3O4 NPs were characterized by ultraviolet-visible (UV-Vis) spectroscopy, FT-IR spectroscopy, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), dynamic light scattering (DLS), zeta potential analysis, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The localized surface plasmon resonance (LSPR) performance of the Fe3O4 NPs was examined. It has been shown that the biosynthesized Fe3O4 NPs once dispersed in water can raise the temperature of water significantly when they absorb solar radiation through surface plasmon resonance (SPR). The impact of the pH value on the Fe3O4 NPs was also investigated. It has been shown that the optimum pH value among the examined pH values was pH 6. At this pH, the biosynthesized Fe3O4 NPs were able to increase the temperature of water from 25 °C to ∼36 °C. This dramatic increase in temperature was owing to the Fe3O4 NPs synthesized at pH 6 which acquired high crystallinity, monodispersity, high purity, minimum agglomeration, a small particle size, and high stability. In addition, the mechanism of converting solar energy to thermal energy has been discussed intensively. To the best of our knowledge, this study is unique and the novelty of this investigation is that Fe3O4 NPs acquire plasmonic-like properties under solar radiation. Also, they are anticipated to be an innovative photothermal adaptation material for solar-based water heating and heat absorption.

INVESTIGATINGTHE IMPACT OF GROWTH TEMPERATURES ON THE ZNO NANORODS PROPERTIES GROWN WITH SIMPLEST SPRAY TECHNIQUE

2023-02
Science Journal pf University of Zakho (القضية : 1) (الحجم : 11)
The simplest chemical spray approach has been used to grow the zinc oxide (ZnO) nanorods (NRs). For spraying, a basic perfumeautomizer was employed. Additionally, utilizing a variety of characterizationtechniques, the effects of various growthtemperatures on the ZnO NRs properties were looked into and evaluated. The results of the investigation demonstratedthat the growingtemperature significantly affects all-characteristicsproperties of the ZnO NRsfabricatedusing the most straightforward spray approach. At various growth temperatures, the average diameters (size) and average crystallinesizes alongwith(002) of grown ZnO NRs were in the ranges of (47.89-51.29) nm and (44.128-52.565) nm, respectively. The hexagonal wurtziteplane was the optimum direction for ZnO NRs to be oriented, and as growthtemperatures are raised. Theabsorption edge changed toward longer wavelengthsandas growth temperature increased,the average absorbance also increased.The optical analysis reveals that the direct Eg.of the produced ZnO NRs lies in the (3.182-3.250) eV range

Characterization of green synthesized of ZnO nanoparticles by using pinus brutia leaves extracts

2023-01
Journal of Molecular Structure (الحجم : 1280)
Zinc oxide (ZnO) nanoparticles have been synthesized by the leaf extracts of the Pinus Brutia (PB) Tree. The impact of the Pinus Brutia (PB) tree extracts and several pH values of the green fabrication mixture (6 to 12) on the ZnO NPs' characteristics has been investigated using several characterization techniques. The obtained results of both analysis of FTIR and UV–Visible spectroscopies of the acquired chosen plant, PB, were demonstrated and proposed to be a better option for the GS ZnO NPs at various pH levels. The UV–Visible spectrum of PB tree leaf extracts displayed one strong absorption peak at 275.3 nm at ambient temperature. The obtained FESEM results analysis demonstrated that the pH values have a noticeable and huge impact affecting the morphology, orientation, shape, and dimensions of the Green Synthesized (GS) ZnO NPs, which are spherical in form and range in size from (37.47 to 73.70 nm). Additionally, the XRD data demonstrate that the produced GS ZnO NPs are GS ZnO that has hexagonal and wurtzite crystal structure, having particle sizes along the (002) peak within the (16.9–24.15) nm range. The UV–Visible analysis of the synthetic GS ZnO NPs revealed a significant peak for ZnO NPs made at various pH levels; the absorption is high in the UV area of less than (400 nm), and with a low absorption rate in the visible range. The band-gap energy (Eg) measured is in the (2.6–2.724) eV range. Additionally, the FTIR analysis of GS ZnO nanoparticles at various pH levels revealed no apparent peak throughout the visible range, demonstrating pure GS ZnO nanoparticles produced by employing PB tree leaf extracts. According to the results of the GS ZnO NP investigations, the GS ZnO NPs produced at pH 8 showed good quality and good improvement in comparison to the ZnO NPs produced at other pH values,
2022

Biosynthesis and Characterization of ZnO Nanoparticles by using Leaf Extraction of Allium Calocephalum Wendelbow Plant

2022-08
Passer Journal (القضية : 2) (الحجم : 4)
Zinc Oxide (ZnO) nanoparticles (NPs) were biosynthesized by using a leaf extract of Allium Calocephalum Wendelbow (ACW) plant. The impact of various zinc salts on the characteristic properties of synthesized ZnO NPs and which salt is more suitable for the synthesis of ZnO NPs were investigated. The used different zinc salts were Zinc Nitrate hexahydrate (ZNH), Zinc Acetate (ZA), and Zinc Chloride (ZC). The properties of synthesized NPs were studied using a variety of characterization techniques. The FTIR analysis and UV-Visible spectroscopy of ACW plant leaf extract proved to suggest this extract is a better choice for the green synthesis of ZnO NPs. The UV–Visible spectra of leaf extract showed two distinct absorption peaks in the region of 262 nm and 350 nm at ambient temperature. The FE-SEM analysis revealed a spherical form of ZnO NPs having an (average) mean size in the range of (21.61-63.12) nm. XRD results revealed the formation of a hexagonal wurtzite structure. The crystal size of produced ZnO NPs along the (002) diffraction peak was in the range of (16.91 to 28.19) nm for different Zinc salt. The EDX analysis shows that the produced ZnO NPs are very pure. The FTIR results displayed there is no obvious peak in the monitoring range, suggesting that the ZnO NPs created via using ACW Leaf Extract. The UV-Vis. results of ZnO NPs showed that the sharpness in this region, exciton absorption, and UV absorption edge were found (381-397) nm, which is corresponding to the Eg of the ZnO NPs, and the investigated Eg of ZnO NPs was in the range of (3.12-3.25) eV. All obtained results of the fabricated ZnO NPs, the ZnO NPs synthesized from zinc salt which is the zinc Nitrate hexahydrate showed very high-quality and improved compared to ZnO NPs synthesized from other zinc salts.

Green Synthesis and Characterization of ZnO Nanoparticles by Using Thyme Plant Leaf Extract

2022-08
Photonics (القضية : 8) (الحجم : 9)
Zinc oxide (ZnO) nanoparticles (NPs) were fabricated by using leaves extracted from the thyme plant by employing a green method. The influence of several calcination (annealing) temperatures on the characteristic properties of fabricated ZnO NPs and the optimum calcination temperature for growing ZnO NPs were studied and reported. The studied calcination temperatures were 150 °C, 250 °C, 350 °C, and 450 °C. Different characterization techniques were used to study and examine the properties of biosynthesized ZnO NPs by using thyme plant leaf extract. The results of each UV-Vis analysis and FTIR spectrum of the leaf extract of the thyme plant confirmed and suggested that the selected leaf extract of thyme is a practicable choice for green synthesis of ZnO NPs. The investigated UV-Vis spectra of plant leaf extract displayed two strong absorption peaks at 266 nm and 313 nm at ambient temperature. The results of FESEM images showed that the calcination temperature has a significant and large effect on the morphology, size, shape, and orientation of ZnO NPs, which have a spherical shape with an average size in the range of 39.4–51.86 nm. In addition, the XRD results confirm that the ZnO NPs formed are pure ZnO with wurtzite hexagonal structure with particle size along the (002) peak in the range of 35.20–243.3 nm. The results of UV-Vis of ZnO NPs displayed a strong peak for all ZnO NPs produced at different calcination temperatures, a high absorbance in the UV region below 400 nm, and a low absorbance rate in the visible range. The obtained energy band gap (Eg) was in the range of 2.645–2.7 eV. In addition, the results of the FTIR spectra of ZnO NPs at different calcination temperatures revealed there was no discernible peak in the monitoring range, which indicated the purity of the ZnO nanoparticles generated via using thyme leaf extract. In addition, from all obtained results of the fabricated ZnO NPs, the ZnO NPs synthesized at the calcination temperature of 450 °C showed a high quality and improvement compared to the ZnO NPs synthesized at other calcination temperatures

Synthesis and characterization of ZnO nanoflowers by using simple spray pyrolysis technique

2022-03
Solid-State Electronics (الحجم : 189)
For perhaps the first time, we documented the manufacturing of a Ultraviolet detector focused on ZnO nanoflowers utilized a simple spray pyrolysis process on porous silicon substrates. The morphological, structural, and optical characteristics of the sample were investigated using FESEM, X-ray system, photoluminescence spectroscopy (PL), and a UV–vis spectroscopy. The device demonstrated 3.07 × 103 sensitivity when exposed to 355 nm UV-light (1.24 mW/cm2) at 3 applied voltages. In contrast, dark current was 2.8 × 10−6 A, and the photodetector's internal gain was 12.75. Moreover, the rise time and full time were determined to be 1.2 sec and 1.8 sec under UV-light (355 nm, 1.24 mW/cm2) at 3 V applied voltages. Every-one of these results indicates that such a high quality Ultraviolet-detector could become a reasonable alternative for industrially interconnected photo-electronic application fields as a low-cost UV detector.
2021

Impact of Radio Frequency Plasma Power on the Structure, Crystallinity, Dislocation Density, and the Energy Band Gap of ZnO Nanostructure

2021-11
ACS Omega (القضية : 7) (الحجم : 6)
The aim of this study is to investigate the effect of radio frequency (RF) plasma power on the morphology, crystal structure, elemental chemical composition, and optical properties of ZnO nanostructure using a direct current magnetron sputtering technique. This study emphasized that the growth rate and surface morphology of the polycrystalline ZnO were enhanced as the radio frequency (RF) plasma power increased. This can be observed by fixing other parameters such as the growth time, substrate temperature, and chamber partial pressure. The RF plasma power alteration from 150 to 300 W can produce uniform nanograin, spheroid, and nanorods. Additionally, the RF plasma power alteration leads to the alteration in the ZnO nanorod diameter from 14 to 202 nm. It was observed that the XRD intensities are increased at higher plasma powers. This, perhaps, can be inferred from the transformation of the granular microcrystals to the needlelike or platelike large crystals, as already examined using SEM images. This also has an impact on the average crystalline size, which increased from 10 to 40 nm on increasing the RF plasma power. Moreover, the increase of the RF plasma power has an obvious impact upon the optical band-gap energy, which was accordingly decreased from 3.26 to 3.22 eV. Finally, the absorption band edge was shifted to a lower-energy region due to the quantum size effect at the nanorange.

Synthesis and characterization of lead oxide nanostructures for radiation attenuation application

2021-04
Materials Science in Semiconductor Processing (القضية : 1) (الحجم : 130)
In this study, lead oxide nanostructures (PbO NSs) were synthesized using chemical bath deposition method (CBD). The physical vapor deposition (PVD) technique used to deposit lead oxide seed-layer on the glass substrates. The effects of different deposition time on the morphology, structural and optical properties of lead oxide NSs were studied. Also, the radiation attention coefficient was measured based on synthesized lead oxide NSs with different deposition times. It was observed the alteration of growth time from 5 min to 20 min leads to significant change in morphology from nanofiber like lead oxide structure to the nanoflower like PbO structure. The XRD results, displayed the lead oxide NSs were indexed as Pb3O4 polycrystalline tetragonal phase. Also, the crystal size was in the range of (15.37–85.68) nm, and the growth rate was gradually decreased from 1.9 nm/min to 0.4 nm/min with deposition time from 5 min to 20 min. The synthesized PbO NSs have high transmittance (~80%) in the visible spectrum and low transmittance in the UV region. The energy band gap (Eg) values of the PbO NSs were changed from (2.20–2.36) eV with increasing growth time up to 20 min. The fabricated PbO NSs exhibited a significant performance in radiation shielding. The average radiation attenuation was changed from (14.592–48.642) count/sec as the deposition time increased from 5 min to 20 min. The higher rate of radiation attenuation for PbO NSs was observed at 10 min of deposition time and it was about 14.592 count/sec. The linear attenuation coefficient and half value layer were altered in the range of (226.132 m-1 -1142 m-1) × 104 and (6.0671–30.646) × 10−8, respectively. Also, the minimum and maximum transmission factor was observed for lead oxide NSs fabricated with 10 min and 20 min respectively. In addition, the maximum radiation protection efficiency was estimated for lead oxide NSs at 10 min and it was about 70%.

Fabrication and Characterization of High-Quality UV Photodetectors Based ZnO Nanorods Using Traditional and Modified Chemical Bath Deposition Methods

2021-03
Nanomaterials (القضية : 3) (الحجم : 11)
Ultraviolet (UV) photodetectors (PDs) based on high-quality well-aligned ZnO nanorods (NRs) were fabricated using both modified and conventional chemical bath deposition (CBD) methods. The modified chemical bath deposition (M-CBD) method was made by adding air bubbles to the growth solution during the CBD process. The viability and effectiveness of M-CBD were examined by developing UV PDs based on ZnO NRs. The ZnO nano-seed layer was coated on a glass substrate utilizing radiofrequency (RF) sputtering. The impact of the different growth-times on morphology, growth rate, crystal structure, and optical and chemical properties were investigated systematically using different characterization techniques, such as field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD) analysis, UV–VIS double beam spectrometer, and energy dispersive X-ray analysis (EDX), respectively. The Al/ZnO UV PDs based on ZnO nanorods were fabricated with optimum growth conditions through the two methods of preparation. This study showed that the synthesized ZnO NRs using the M-CBD method for different growth times possess better properties than the conventional method under similar deposition conditions. Despite having the highest aspect ratio and growth rate of ZnO NRs, which were found at 4 h growth duration for both methods, the aspect ratio of ZnO NRs using the M-CBD technique was comparatively higher than the conventional CBD method. Besides, the UV PDs fabricated by the M-CBD method at 5 V bias voltage showed high sensitivity, short response time, quick recovery time, high gain, low dark current, and high photocurrent compared with the UV PD device fabricated by the conventional CBD method.

Effect of different pH values on growth solutions for the ZnO nanostructures

2021-03
Chinese Journal of Physics (الحجم : 71)
In this study, high quality zinc oxide (ZnO) nanostructures were synthesized on glass slide substrates using modified chemical bath deposition (M-CBD) method at low temperature. Through the M-CBD technique the air bubbles will be injected into aqueous growth solution. The RF magnetron sputtering method was utlized to grow ZnO seed layer on the glass substrates. The effect of different pH values of aqueous growth solution on the morphology, elemental chemical composition, crystal structural and the optical properties of ZnO nanostructures have been investigated using field emission-scanning electron microscopy (FE-SEM), Energy dispersive analysis (EDX), X-ray diffraction (XRD), and UV-Visible Spectrometer, respectively. It was observed that altering pH values from acidic to alkaline (basic) by using ammonia solution (NH3) induced the significant change in morphology from nanorods like ZnO to nano-amber flush rose like ZnO structures. Furthermore, increased pH values had an effect on the influence intensity of the preferred orientation plane (002) and average transmittance spectrum. Whilst the absorption band edge has been shifted to a lower energy region due to the quantum size effect. It was also found that the crystal size fluctuated between 36.30 nm and 84.33 nm with a different values of pH from 6.7 to 12. The ZnO synthesized at 6.7 of pH provided the best results regarding the high aspect ratio,structural and optical properties. At this pH value, ZnO growth revealed the nanorod structure with small diameters, size and a higher energy band gap value.

Synthesis of lead oxide thin films by using physical vapor deposition technique

2021-02
Materials Today: Proceedings
In this study, the lead oxide thin films were synthesized upon the glass slide substrate by using the physical vapor deposition (PVD) technique. The molybdenum boat was used to heat the high purity lead (Pb) powder with 5 × 10−5 mbar vacuum pressure of the PVD chamber. The morphological, structural, and optical properties have been examined and characterized by employing different characterizations techniques. The results found that the crystal size and interplanar distance of lead oxide thin film were about 1.695 nm and 3.55 Å, respectively. The lead oxide thin film has high average transmittance in the visible region which was about (∼80%) and low average transmittance in the UV region. Also, the energy band gap (Eg) of the deposited lead oxide thin film was 2.35 eV.

Fabrication and Characterization of High-Quality UV Photodetectors Based ZnO Nanorods Using Traditional and Modified Chemical Bath Deposition Methods

2021-02
Sensors and Actuators A: Physical (القضية : 1) (الحجم : 323)
Ultraviolet (UV) photodetectors (PDs) based on high-quality well-aligned ZnO nanorods (NRs) were fabricated using both modified and conventional chemical bath deposition (CBD) methods. The modified chemical bath deposition (M-CBD) method was made by adding air bubbles to the growth solution during the CBD process. The viability and effectiveness of M-CBD were examined by developing UV PDs based on ZnO NRs. The ZnO nano-seed layer was coated on a glass substrate utilizing radiofrequency (RF) sputtering. The impact of the different growth-times on morphology, growth rate, crystal structure, and optical and chemical properties were investigated systematically using different characterization techniques, such as field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD) analysis, UV–VIS double beam spectrometer, and energy dispersive X-ray analysis (EDX), respectively. The Al/ZnO UV PDs based on ZnO nanorods were fabricated with optimum growth conditions through the two methods of preparation. This study showed that the synthesized ZnO NRs using the M-CBD method for different growth times possess better properties than the conventional method under similar deposition conditions. Despite having the highest aspect ratio and growth rate of ZnO NRs, which were found at 4 h growth duration for both methods, the aspect ratio of ZnO NRs using the M-CBD technique was comparatively higher than the conventional CBD method. Besides, the UV PDs fabricated by the M-CBD method at 5 V bias voltage showed high sensitivity, short response time, quick recovery time, high gain, low dark current, and high photocurrent compared with the UV PD device fabricated by the conventional CBD method.

Effect of Growth Temperature on Morphological, Structural, and Optical Properties of ZnO Nanorods Using Modified Chemical Bath Deposition Method

2021-01
Journal of Electronic Materials
Zinc oxide (ZnO) nanorods (NRs) have been investigated as a function of different growth temperature using modified chemical bath deposition (M-CBD) method. In this study, air bubbles were utilized inside the growth solution as an original modified process. The synthesis of ZnO NRs was carried out through two steps. The first step was deposition of the ZnO seed layer on the glass substrate, while the second step was growing the ZnO NRs on the seeded substrate. The impacts of the growth temperature on the morphology and crystal structure of the ZnO samples were investigated using field emission scanning electron microscopy and x-ray diffraction. UV–Vis spectroscopy was also utilized to characterize the optical properties of the ZnO NRs. The results showed that the growth of the ZnO samples is a NRs-like shape. The ZnO samples possess the hexagonal wurtzite structure with high crystal quality, and no other phases from the impurity were observed. Additionally,the ZnO NRs were found to be well oriented along te (002) planes with diameters ranging from 71 nm to 328 nm and length from 294 nm to 2475 nm, while the aspect ratio was up to 25 with different growth temperatures. However, the UV–Vis spectrum showed that the optical transmittance of the ZnO NRs dropped from ~ 66% to ~ 3.3%, and the absorption band edge had been shifted to a lower-energy region as the growth temperature increased from 65°C to 95°C. This is possibly due to the scattering increase and absorption light from voids, grain size, and thickness of the ZnO NRs. Therefore, it has been demonstrated that the ZnO NRs grown by the M-CBD method at a growth temperature of 95°C gives the most favorable result, since the NRs possess the optimum, homogenous, and uniform distribution with a higher aspect ratio, crystal quality, crystal size, and band gap energy.
2020

Synthesis and Characterizations of ZnO Thin Films Grown by Physical Vapor Deposition Technique

2020-12
JOURNAL OF APPLIED SCIENCE AND TECHNOLOGY TRENDS (القضية : 04) (الحجم : 01)
In the current study, Zinc oxide (ZnO) thin films have been synthesized over the whole the glass-slide substrate by utilizing the physical vapor deposition (PVD) technique. The Zinc (Zn) seed layer was deposited by heating the high purity Zn powder by using a molybdenum (Mo) boat at 37.503×10-3 Torr vacuum pressure of the PVD chamber. The ZnO thin films were fabricated by oxidation of the Zn seed layer coated glass-slide substrate at 400 οC. The morphological, chemical compositions, crystal quality, structural and optical properties of fabricated ZnO thin film were characterized and studied utilizing several characterization techniques. The results found that the high distribution density, homogenous, uniform, and high-quality ZnO thin film was grown over the entire substrate. The synthesized ZnO thin film with a thickness of 130 nm was grown with high purity and polycrystalline hexagonal-Wurtzite phase of ZnO. The sharp, and dominant diffraction peak was observed at peak position 34.3375 along (002) plane and c-axis. The investigated crystal size, dislocation density, and interplanar spacing were about 13.33 nm, 5.63×10-5 Å, and 2.609 Å, respectively. Also, UV-visible spectroscopy results show the high transmittance and low absorbance in the visible (Vis.) region and were about 90%, and the transmittance decreases sharply near the UV region at a wavelength around 383 nm. Besides, obtained the energy band-gap (Eg) was about 3.24 eV.

The Influence of Various Reactants in the Growth Solution on the Morphological and Structural Properties of ZnO Nanorods

2020-10
Passer Journal (القضية : 2) (الحجم : 2)
In the current work, the effect of three different Zinc (Zn) salts as reactants precursors in the growth solution on the characteristic properties of the Zinc oxide (ZnO) nanorods (NRs) was investigated and reported. High quality hexagonal ZnO NRs have been grown on the glass-slide substrates via the chemical-bath deposition (CBD) approach at 90 ºC. The radio-frequency sputtering (RF) technique has been used to coat the 150 nm of ZnO nano-seed layer over the whole glass-slide substrates. The Field-emission scanning electron microscopy (FESEM), the Energy-dispersive characterization (EDX), and the X-ray diffraction (XRD) characterizations have been used to characterize and examination of the morphological, chemical compositional, and structural characteristics with ZnO hexagonal-wurtzite structure of the NRs. The used zinc salts were Zinc-nitrate Hexahydrate (ZNH), Zinc-acetate (ZA), and Zinc-chloride (ZC). The FESEM and XRD results indicated that the change in types of Zinc salts with Methenamine as reactants precursors in the growth (deposition) solution have a remarkable and significant impact on the surface topography (morphology) characteristics and structural characteristics of synthesized ZnO NRs. The average size and average length of the grown ZnO NRs were in the range of (91-529) nm and (1008-3189) nm, respectively. The high aspect ratio was obtained of ZnO NRs synthesized from Zinc-nitrate Hexahydrate salt and was about 11. The highest growth rate was investigated ZnO NRs synthesized from Zinc-chloride salt and was about 17.716 nm/min. The average crystalline size of synthesized ZnO nanorods was in the range (48.35-56.06) nm

Investigation the Effect of Chemical Composition of Perovskite Layer on Performance of Perovskite Solar Cells

2020-07
Journal of Emerging Technologies and Innovative Research (JETIR) (القضية : 7) (الحجم : 7)
In this work, a modest method for creating Perovskite solar cells (PSCs) by recycling car batteries is used. Trying to get rid of some structures or materials which are harm to the environment. However, by reusing car batteries we will avoid the disposal of toxic battery materials and provide an alternative technique, readily-available Pb source for fabricating PSCs. Perovskite solar cells (PSCs) were prepared by two-step spin coating solution method on the FTO glass substrate. Lead iodide (PbI2) and methyl-ammonum iodide (CH3NH3I) used to form the structure of the precursor (CH3NH3PbI3). The photovoltaic performance of PSCs and the effect of chemical composition of perovskite layer on performance of PSCs was investigated. Characterization of PSCs by using X-ray diffraction, SEM and the effect of chemical composition on of MAPI films was achieved. It was found that the thickness ratio of (PbI2/MAI) with 3.0:1 have highest fill factor and maximum efficiency.

The effect of different substrate-inclined angles on the characteristic properties of ZnO nanorods for UV photodetectors applications

2020-07
Journal of Materials Science: Materials in Electronics
The effect of six different substrate-inclined angle with the vessel on the characteristics properties of the Zinc Oxide (ZnO) nanorods was explored and reported. The vertically well-aligned ZnO Nanorods (NRs) were synthesized on glass substrates by using the low-cost chemical bath deposition (CBD) method at 90 °C. The RF magnetron sputtering has been employed to deposit the ZnO nanoseed layer on glass substrates and electrodes for UV photodetectors (PDs) devices. The morphological, structural, and optical properties of the synthesized ZnO NRs have been investigated using various characterization techniques for different substrate- inclined angles. Also, the high-quality UV photodetector-based ZnO NRs have been fabricated for the optimum substrate-inclined angle of 70° with the vessel by applying a different bias voltage. The results found that variation of substrate-inclined angles have the remarkable and significant effect on the shape, size, length, alignment, density distribution, structure, lattice parameters, crystalline size, energy band gap (Eg), and optical properties of ZnO NRs. The average diameters and length of grown ZnO NRs were in the range of (58–249) nm and (303–2518) nm, respectively. The high aspect ratio, length, and growth rate were observed for ZnO nanorods grown at 70° substrate-inclined angle. The preferred orientation of ZnO NRs was along (002) hexagonal wurtzite plane and the intensity of (002) diffraction peak for ZnO NRs was increased with increasing substrate-inclined angles. The average crystalline size was in range of (46.7–58.8) nm. The average transmittance of ZnO NRs showed a reduction in the range of (44.5–3.3)% as the substrate angle increased. The optical studies show that the synthesized ZnO NRs have the direct Eg in the range of (3.16–3.254) eV. The fabricated UV PD-based ZnO NRs showed high performance and quality. The different bias voltage study shows that the ZnO nanorod UV PD has higher stability and repeatability at 5 V bias voltage. The PDs device exhibited the responsivity value of 3.49903 A/W to 390 nm light wavelength at 5 V, which is higher than those reported for UV PDs-based ZnO NRs. At 5 V bias voltages, the fabricated UV PDs showed a faster response and recovery times of 0.3402 S and 0.1639 S, respectively.

STUDY THE OPTICAL PROPERTIES OF THE VARIOUS DEPOSITION SOLUTIONS OF ZnO NANORODS GROWN ON GLASS SUBSTRATE USING CHEMICAL BATH DEPOSITION TECHNIQUE

2020-06
Journal of Ovonic Research (القضية : 3) (الحجم : 16)
In this study, two-step chemical bath deposition (CBD) technique has been employed for the fabrication of Zinc Oxide (ZnO) nanorods at low temperature. The ZnO nano-seed layer was deposited on the glass substrate using a radio frequency sputtering discharge technique. The impact of three zinc salts with Hexamethylenetetramine (HMTA) on the properties of ZnO nanorods have been investigated. The double beam UV visible (UV4100) spectrometer, micro-Raman scattering, and Field emission scanning electron microscopy (FESEM) were used to characterize and study the optical properties, energy band gap, defects, Raman spectra, phase orientation, quality of material, the interaction of phonons, transport properties, and the morphology of synthesized ZnO nanorods (NRs), respectively. The three zinc salts are Zinc Nitrate Hexahydrate, Zinc Acetate, and Zinc Chloride. The results found that the variation in zinc salts types with Hexamethylenetetramine as deposition solution is play a very important impact on the structures of fabricated ZnO nanorods that effected directly on the optical properties, energy band, material quality, and phase orientation of ZnO NRs. Also, from UV measurement the optical properties and energy band gap of produced ZnO nanorods are changed with changing the zinc salt as a precursor of deposition solution.

Biosynthesis, Characterization and Mechanism of Formation of ZnO Nanoparticles Using Petroselinum Crispum Leaf Extract

2020-06
Current Organic Synthesis (القضية : 3) (الحجم : 17)
The study aimed at synthesizing ZnO nanoparticles by using Petroselinum crispum extract, commonly known as parsley, as a source of biosynthesis without utilizing chemical agents for reducing, capping, and stabilizing agent.

Enhancement of ZnO Nanorods Properties Using Modified Chemical Bath Deposition Method: Effect of Precursor Concentration

2020-05
Crystals (القضية : 5) (الحجم : 10)
In this study, the effects of different precursor concentrations on the growth and characteristics properties of the zinc oxide (ZnO) nanorods (NRs) synthesized by using modified and conventional chemical bath deposition (CBD) methods were investigated. The morphologic, structural and optical properties of synthesized ZnO NRs with different precursor concentrations were studied using various characterization techniques. The experimental results show that the varying precursor concentration of the reactants has a remarkable and significant effect on the growth and characteristics properties of ZnO NRs. In addition, the characteristic properties of ZnO NRs grown using the modified method showed significantly improved and enhanced properties. The average length of grown ZnO NRs increased with increased precursor concentration; it can be seen that longer ZnO NRs have been investigated using the modified CBD methods. The ZnO NRs synthesized at 0.05 M using the modified method were grown with high aspect ratios than the ZnO NRs grown using conventional means which were 25 and 11, respectively. The growth rate increased with increased precursor concentration; it can be observed that a higher growth rate was seen using the modification CBD method. Furthermore, XRD results for the two cases reveal that the grown ZnO samples were a nanorod-like in shape and possessed a hexagonal wurtzite structure with high crystal quality. No other phases from the impurity were observed. The diffraction peaks along (002) plane became higher, sharper and narrower as precursor concentration increased, suggesting that the crystalline quality of ZnO NRs grown using the modified method was more enhanced and better than conventional methods. However, optical studies show that the transmittance at each concentration was more than two times higher than the transmittance using the modified CBD method. In addition, optical studies demonstrated that the ZnO NRs grown by using modified and conventional methods had a direct Eg in the range of (3.2–3.26) eV and (3.15–3.19) eV, respectively. It was demonstrated in two methods that ZnO NRs grown at a precursor concentration 0.05 M gave the most favorable result, since the NRs had best characteristic properties.

SYNTHESIS OF RUTILE-TiO2 NANOROD ARRAYS FOR EFFICIENT SOLAR WATER SPLITTING VIA MICROWAVE-ASSISTED HYDROTHERMAL METHOD

2020-03
Digest Journal of Nanomaterials and Biostructures (القضية : 1) (الحجم : 15)
Using a microwave-assisted ‎hydro thermal method (MWAHM) a single crystalline of vertically aligned TiO nanorod (NR) ‎arrays has been achieved via the novel ultra-rapid synthetic ‎method for the production. High-quality NR arrays with ‎controlled film thickness were achieved with fine control of the ‎growth conditions as well. The effect of the different reaction conditions of ‎MWAHM such as reaction time and growth temperature on the ‎morphology, crystal orientation, and photo catalytic activity have ‎been systematically investigated. In a typical condition of the ‎MWAHM using 0.4 cm 2 of titanium(IV) n-butoxide (TBO) at ‎‎180 °C for 40 minutes, a small diameter of 124 nm and short length ‎‎2.93 µm of TiO 2 nanorods, are grown on fluorine-doped tin oxide (FTO) substrate. However, the photo current ‎density produced TiO2 NRs of 2.90 mA cm with a maximum ‎photo conversion efficiency of about 2.7% which confers excellent ‎photoelectrochemical performance. In comparison with the typical ‎hydro thermal method (HM) synthesized NRs, the ultra-fast ‎MWAHM synthesized NRs offers five times more efficiency ‎photoelectrochemical (PEC) water splitting than the hydro thermal ‎method (HM).‎‎The results suggest that these dense and aligned one-dimensional ‎TiO2 nanorods are promising for hydrogen generation from water ‎splitting based on PEC cells.
2018

INVESTIGATION OF OPTICAL PROPERTIES OF ZnO NANORODS GROWN ON DIFFERENT SUBSTRATES

2018-12
Science Journal of University of Zakho (القضية : 4) (الحجم : 6)
ZnO nanorods arrays are synthesized over the different substrates namely; Indium Tin Oxide (ITO), Kapton Tape (KT), Polyethylene terephthalate (PET), Porous Silicon (PS) and Silicon (Si) using modified chemical bath deposition (MCBD) method at 95 ºC for 4 h. The MCBD is the air bubbles inside growth solution during CBD process. The ZnO nano-seed layers are coated on different substrates using RF magnetron sputtering technique. The optical properties (transmittance, reflectance and energy band gap) and surface morphology of ZnO nanorods grown on different substrates have been investigated in details by using UV-Visible Spectrometer and Field emission scanning electron microscopy (FESEM), respectively. The results found that the morphology and diameter of ZnO nanorods is closely concerned with the nature of substrates. Also it is indicated that the substrate has strong and important impact on the growth, optical properties, Eg and quality of synthesized ZnO nanorods (NRs). The higher transmittance has been observed for ZnO NRs grown over KT substrates and is about (~ 33 %). The average transmittance decreases sharply near UV region at wavelength around 393 nm for ZnO nanorods grown on ITO substrate. However, for PET and KT substrates, the transmittance decreases sharply near visible region around 401nm and 498 nm, respectively. Besides, the ZnO NRs grown on PS substrate have the strong reflectance characteristics after approximately 395 nm, and then decreases in the wavelength range of 410 nm to 700 nm. On the other hand, the strong reflectance property of ZnO NRs grown on Si substrate is observed at 400 nm. Also, the minimum and maximum Eg are obtained for ZnO nanorods that fabricated on the KT substrate and porous silicon substrate, respectively.
2017

EFFECT OF THE GROWTH TIME ON THE OPTICAL PROPERTIES OF ZNO NANORODS GROWN BY LOW TEMPERATURE METHOD

2017-10
Digest Journal of Nanomaterials and Biostructures (القضية : 4) (الحجم : 12)
ZnO nanorods have been synthesized on glass substrate by low-cost two step chemical bath deposition (CBD) method at low temperature. The ZnO seed layers have been coated on glass substrate by RF magnetron techniques with power 150 watt for 15 min. The influence of different growth time on the optical properties, energy band gap, Raman spectra and surface morphology of ZnO nanorods are investigated. The growth time are (0.5, 1, 2, 3, 4 and 5) h. The double beam UV visible (UV-5000) , Raman Spectroscopy and field emission scanning electron microscopy have been used to characterize the optical properties (absorption and transmission), energy band gap, Raman spectra, surface morphology, diameter, distribution and homogeneity of produced ZnO nanorods. The results found that the growth time have significant effect on the optical properties, energy band gap, Raman modes, aligned, surface morphology, diameter, ZnO distribution and density. And It is observed that the absorbance of the growth times 4 and 5 h are higher than the other growth times of ZnO nanorods, which showed the good crystallinity of the other samples. The transmittance decreases sharply near UV region at wavelength around 385 nm due to the optical band gap absorption.The obtained energy band gap of ZnO nanorods decreases with increase in the growth time from 3.25 eV to 3.18 eV. From result, it was investigated that the growth time caused the average crystalline size increases and decreases defects causing the energy band gap decreased. From Raman spectra , it observed that the dominant and sharp peaks at approximately 100 cm-1c and 437 cm forthe ZnO nanorods grown of 4 h and 5 h as a growth times, which are corresponds to the intrinsic characteristics of the Raman active E2(low) and E modes of the hexagonal wurtzite ZnO, respectivly Also FESEM results shows that the growth time has a good playing role on the nanostructure growth orientation of the ZnO nanorods.

Fabrication, characterization of ZnO nanorods on the flexible substrate (Kapton tape) via chemical bath deposition for UV photodetector applications

2017-08
AIP Conference Proceedings, International Conference on Applied Physics and Engineering (ICAPE2016) (القضية : 020004) (الحجم : 1875)
One dimensional ZnO nanorods have been synthesized on flexible substrate. The substrate is Kapton Tape (KT). ZnO Nanorods are produced by using low cost chemical bath deposition method at low temperature. The investigation of the effect of substrate on the morphological, elementary composition, structural characteristics and Raman spectroscopy of ZnO nanorods has been done. Field emission scanning electron microscopy (FESEM), Energy Dispersive analysis (EDX), X-ray diffraction (XRD) and Raman spectroscopy measurements are employed to examine the morphological, compositional and structural haracteristics with hexagonal wurtzite structure of the ZnO nanorods arrays. The results found that the average diameter of ZnO nanorods is found to be closely related to the substrate nature. It is concluded that the substrate can effect on the ZnO nanorods growth remarkably and the selective growth of ZnO nanorods is possible through the choice of the substrate. The crystallite size and the lattice constants of the synthesis ZnO nanorods are obtained based on the XRD data. The found results revealed that the increase in the crystallite size is strongly associated with the type of substrate.

THE INFLUENCE OF THE GROWTH TIME ON THE SIZE AND ALIGNMENT OFZnO NANORODS

2017-03
Science Journal of University of Zakho (القضية : 1) (الحجم : 5)
Vertically aligned ZnO nanorods arrays were synthesized on glass substrates. ZnO seed layers were prepared on glass substrate by RF Sputtering technique. ZnO nanorods synthesized using low-cost chemical bath deposition method at low temperature (95 ºC). The effect of the different growth time such as (0.5, 1, 2, 3, 4 and 5) h on the morphology, elemental chemical composition and structure of the ZnO nanorods were obtained systemically, and tested by Field emission scanning electron microscopy (FESEM), Energy dispersive analysis (EDX), and XRD measurements. The results found that the ZnO nanorods with hexagonal wurtzite structure grow vertically on the glass substrates. Most of the prepared samples have strong and sharp (002) peak intensities and the diffraction peaks (002) become higher and narrower as growth time increasing, obtaining that the ZnO crystalline quality became better with growth time increasing. The growth rate was decreases with increasing growth time, and the high aspect ratio was found at 4 h as a growth time. The size, length and crystalline size of the ZnO nanorods increase with increasing growth time. Furthermore the ZnO nanorods vertically grow at (002) direction along the c-axis on the glass substrate, with elementary chemical compositions of zinc and oxygen only for all prepared samples.
2016

NOVEL PROCESS USING OXYGEN AND AIR BUBBLING IN CHEMICALBATH DEPOSITION METHOD FOR VERTICALLY WELL ALIGNED ARRAYS OF ZnO NANORODS

2016-10
Digest Journal of Nanomaterials and Biostructures (القضية : 4) (الحجم : 11)
Vertically well-aligned ZnO nanorods arrays have been synthesized on ZnO seed layer coated glass substrates at low temperature using modified low-cost chemical bath deposition (CBD) method. The investigation of the influence of no air bubbles, air bubbles and oxygen bubbles inside the CBD reactor on the structural characteristics, morphological (diameter, length, aligned, distribution and homogeneously), elements chemical composition and optical properties of ZnO nanorods have been studied. This new modification of chemical bath deposition method shows the improved results over traditional chemical bath deposition method. The important results of this novel process are the good morphological, structural characteristic and optical properties of ZnO nanorods. These results obtained in just of 3.5 h growing time in the CBD reactor. On this modified CBD the growth time rate decreases about 1.5 h compared with the previous works.

DIFFERENT SUBSTRATES EFFECTS ON THE TOPOGRAPHY AND THE STRUCTURE OF THE ZnO NANORODS GROWN BY CHEMICAL BATH DEPOSITION METHOD

2016-09
Digest Journal of Nanomaterials and Biostructures (القضية : 3) (الحجم : 11)
In this paper, vertically aligned ZnO nanorods arrays were fabricated on different substrates. The substrates are Indium Tin Oxide (ITO) coated glass, polyethylene terephthalate (PET), Silicon (Si), Porous Silicon (PS) and Kapton Tape (KT). Nanorods are fabricated at low temperature by using chemical bath deposition method. The investigation of the effect of substrates on the morphological, elementary composition and structural characteristics of ZnO nanorods has been done. Field emission scanning electron microscopy (FESEM), Energy Dispersive analysis (EDX) and X-ray diffraction (XRD) measurements were used to investigate the morphological, compositional and structural characteristics with hexagonal wurtzite structure of the ZnO nanorods arrays. The average diameter of ZnO nanorods are found to be closely related to the substrates nature. It is concluded that the substrates can effect on the ZnO nanorods growth remarkably and the selective growth of ZnO nanorods is possible through the choice of the substrates. The crystallite size and the lattice constants of the synthesis ZnO nanorods were calculated based on the XRD data. The found results revealed that the increase in the crystallite size is strongly associated with the type of substrate.
2013

DIFFERENT SUBSTRATES EFFECTS ON THE TOPOGRAPHY AND THE STRUCTURE OF THE ZnO NANORODS GROWN BY CHEMICAL BATH DEPOSITION METHOD

2013-06
Digest Journal of Nanomaterials and Biostructures (القضية : 12) (الحجم : 7)
In this paper, vertically aligned ZnO nanorods arrays were fabricated on different substrates. The substrates are Indium Tin Oxide (ITO) coated glass, polyethylenterephthalate (PET), Silicon (Si), Porous Silicon (PS) and Kapton Tape (KT). Nanorodare fabricated at low temperature by using chemical bath deposition method. The investigation of the effect of substrates on the morphological, elementary composition a nstructural characteristics of ZnO nanorods has been done. Field emission scanning electron microscopy (FESEM), Energy Disperse analysis (EDX) and X-ray diffraction (XRD measurements were used to investigate the morphological, compositional and structure characteristics with hexagonal wurtzite structure of the ZnO nanorods arrays. The average diameter of ZnO nanorods are found to be closely related to the substrates nature. It concluded that the substrates can effect on the ZnO nanorods growth remarkably and the selective growth of ZnO nanorods is possible through the choice of the substrates. The crystallite size and the lattice constants of the synthesis ZnO nanorods were calculated based on the XRD data. The found results revealed that the increase in the crystallite size is strongly associated with the type of substrate.

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