Influence of annealing temperature of seed layer on the structural and optical properties of ZnO nanorods synthesized by SILAR and CBD techniques
2024-12-18
ABSTRACT
In this study, zinc oxide nanorods were synthesized using chemical bath deposition with a ZnO
seed layer on glass substrates via successive ionic layer adsorption and reaction. The effect of
annealing temperature on the seed layer was investigated using various characterization tech
niques. Results show that annealing temperature significantly influenced the morphology and
quality of ZnO NRs. As the temperature increased from 0°C to 500°C, the nanorod length grew
from 591 to 1008 nm. Optimal conditions were found at 450°C, with a growth rate of 4.2 nm/min
and an aspect ratio of 11. The crystalline size ranged from 10.56 to 52.93 nm, confirmed by XRD
analysis, showing the hexagonal wurtzite structure. The bandgap energy varied from 3.221 eV to
3.2656 eV, reflecting the impact of annealing on optical properties. Optical transmittance was
highest at 0°C, decreasing from 57% to 13% as the annealing temperature increased.